CHF3 Decomposition by Dielectric Barrier Discharge Reactor

CHF3 Decomposition by Dielectric Barrier Discharge Reactor Decomposition of CHF3 by a Dielectric Barrier Discharge Reactor Duc Ba Nguyen and Won Gyu Lee* Abstract Oxidation of CHF3 was investigated in a dielectric barrier discharge reactor was immersed in an electrical insulating oil. The feed gases was mixed of CHF3, O2 and N2 with O2/N2 ratio of 21/79 volume/volume. The results obtained that 98.98% of CHF3 in the feed gases were destruction under: applied voltage of 7kV, frequency of 30 kHz; total flow rate of 100 ml/min with initial CHF3 concentration of 5%. Herein, selectivity of CO and CO2 in the products was 3.42% and 91.18%, respectively. Decomposition of CHF3 could be increased by improved plasma condition such as increasing applied voltage, increased frequency and decreased initial CHF3 concentration in the feed gases. Keywords: CHF3, dielectric barrier discharge, electrical insulating oil, plasma reaction, oxidation of CHF3 Introduction Decomposition of trifluoromethane (CHF3) is high potential reduce greenhouse gases. Because the 100 years global warming potential of CHF3 is 12000 [1]. Several methods have been employed for the decomposition of CHF3 such as thermal process [2-4], catalyst [5, 6]; plasma or combined plasma with catalyst (CPC) [7-11]. Thermal oxidation is one of effective CHF3 decomposition [12]. However, HF acid and formation fluorinated compounds existed in the exhaust gas stream along with high operation temperature (1473 K) [2]. It mean that the process is high cost, require material reactor and concern environmental. Thus, other process are required for treatment of exhaust gas such as absorbed acids, cooling process and decomposition of fluorinated compounds before ambient atmospheric emission [2, 11]. Catalyst methods could be reduced operation temperatures in the abatement of CHF3. However, HF formation and also operation temperature above 500 0C lead to reducing effective of catalyst [13-15]. Several above challenges could be solved by plasma or CPC, including, non-thermal plasma (NTP) is attractive and effective decomposition of CHF3 [16, 17]. Decomposition of CHF3 in NTP is lead to interaction between of high energy electrons, radicals and gas molecules. Herein, NTP could be generated high energy electr ons and radicals under high energy electrical. Therefore, decomposition of CHF3 could be performed at room temperature, ambient atmospheric pressure, fast conversion and easy realization by plasma method. However, several researchers have been reported the decomposition of CHF3 by catalyst or CPC with several thousand parts per million of CHF3 in the feed gases [18, 19]. It demonstrated that process yields were low. Moreover, the emission source of CHF3 is semiconductor industries, air condition, polystyrene industries and commercial refrigeration. So that the gas waste included CHF3 and air. Therefore, abatement of CHF3 in the gas waste is need before into atmosphere. In this study, decomposition of CHF3 with Zero Air (21% O2 and 79% N2) performed in a coaxial dielectric barrier discharge reactor under initial CHF3 concentration was not less than 5.0% (v/v). The reactor was immersed in an electrically insulating oil bath. Effect of several factors on the reaction investigated, namely, applied voltage, applied frequency, initial CHF3 concentration in the feed gas. These factors were examined on the decomposition of CHF3 and product components. Experimental The schematic of the experiment setup is shown in Fig. 1. A system is composed of four main parts: a feed gas system, an AC high voltage pulse power supply, a plasma reactor, and an analysis system. The reactor has an inner stainless steel stick as the power electrode that is 15 mm in diameter. The power electrode was placed inside a quartz tube as a dielectric barrier. Its outer diameter was 20 mm, and its thickness was 1.5 mm. Therefore, the discharge gap was fixed at 1.0 mm. Copper foil was wrapped around the quartz tube as the ground electrode, and its length was 200 mm. Thus, the discharge volume was about 10 ml. The plasma reactor was immersed in an electrically insulating oil bath (transformed oil provided by Michang Oil, KSC2301). The volume of electrical insulating oil bath was about 5000 ml. AC pulse power supply with 2 kW capacity was used for plasma ignition, which had a supply voltage and a frequency up to 30 kV (peak-to-peak) and 30 kHz, respectively. The electrical power was controlled by manual adjustment of the applied voltage level. The power waveforms were recorded by an oscilloscope (Tektronix 2012B). Fig. 2 showed a typical voltage, current, and discharge power waveforms generated under the process condition: total flow rate of 100 ml/min with CHF3 in the feed of 5% (v/v), frequency of 30 kHz; applied voltage of 7 kV. Discharge power was integral of current and voltage as shown in the equation below: Discharge power (P), (1) All of the experiments were performed at ambient atmospheric pressure and room temperature. The volume of gas products was measured by a soap-bubble flow meter. The composition of the gas products was analyzed by a gas chromatograph (GC, Younglin YL6100GC) equipped with a thermal conductivity detector (TCD) and a flame ionization detector (FID). A CarboxenTM 1010 PLOT capillary column was used in the GC column and the flow rate of Ar as a carrier was 6.0 ml/min. The products of plasma reaction with mixing of CHF3, O2 and N2 included N2O, NO2, COF2, F2, CF4, CO, CO2, CHF3, O2, N2 and so on [19]. However, the GC analysis could detect the reaction products including CO, CO2, and CHF3. According to the analysis of the products, the overall conversion, carbon balance and selectivity were defined as follows: (2) (3) (4) (5) Results and discussion Effect of applied voltage An applied voltage is important factor in the plasma process. Which is usually used to ignite and sustain glow discharge. Moreover, the degree of plasma reaction depend on the level of applied voltage, for example conversion of reactants and selectivity of products [19, 20]. The effect of applied voltage on the reaction was investigated under applied voltage from 4 to 7 kV, total flow rate of 100 ml/min with CHF3 concentration of 5% in the feed gases; frequency of 30 kHz. The results was shown as in fig 3. At applied voltage of 4 kV, the conversion of CHF3 obtained at 0%, however, the conversion of CHF3 was increased sharply from 5 to 7 kV applied voltage in fig 3 (a). The results demonstrated that energy input at applied voltage of 4 kV into discharge zone was not enough for dissociation of gases molecules. It due to lack of electron and radical formation for plasma reaction. However, electron and radicals for plasma reaction could be formed when applied voltage above of 4 kV. In ad dition, bond-dissociation energy of F-CHF2 and H-CF3 were 539.9 and 445.2 kJ/mol-1 at 298 K, respectively [21]. Discharge power increased sharply from 8 to 41 W, when applied voltage increased from 5 to 7 kV. It was caused of increasing CHF3 conversion in these experiments. Consequently, concentration of CHF3 in the gas outlet was 0.054% at applied voltage of 7 kV as shown in fig 3(b). An applied voltage was also effect on the component of gas outlet. The concentration of CO2 were increased significantly by increasing applied voltage from 5 to 7 kV, while, the concentration of CO were changed slightly during those experiments as shown in fig 3(b). In fact that, more radical and molecules in the discharge zone could be formed under high discharge power such as F, H, CF3, CF2, COF2, COF, CO, CO2, F2 and so on [19]. Therefore, conversion of reactants and products formation increased. Moreover, the selectivity of CO2 increased from 40% to 89% when applied voltage from 5 to 6 kV. Consequently, it increased slightly at applied voltage of 7 kV as shown in fig 3 (c). On the contract, the selectivity of CO decreased slightly from 5 to 6 kV and then it decreased gradually at applied voltage of 7 kV. The results due to increasing radical oxygen formation in the discharge zone when applied voltage increased from 5 to 7 kV. Carbon balance decreased slightly, when applied voltag e increased from 6 to 7 kV. It mean that total selectivity of CO and CO2 decreased. In fig 3 (c) shown that decreased selectivity of CO caused of reducing carbon balance. As the results, the maximum conversion of CHF3 obtained at 98.98% under applied voltage of 7 kV, frequency of 30 kHz, total flow rate of 100 ml/min and CHF3 concentration in the feed gases of 5%. Herein, the selectivity of CO2 and CO 91.18% and 3.42% in the product, respectively. Effect of initial CHF3 concentration Conversion of reactants could be improved by reducing initial amount of reactants in the feed. However, it caused of decreasing yield processing. Effect of initial CHF3 concentration on the reactions were investigated under applied voltage of 7 kV, frequency of 30 kHz and total flow rate of 100 ml/min. The results was shown in fig 4. The conversion of CHF3 decreased slightly from 98.98% to 95.94% when initial CHF3 concentration in the feed increased from 5% to 15%. It was as shown in fig 4 (a). The results demonstrated that conversion rate of CHF3 depended slightly on the range of initial CHF3 concentration. It was due to increased amount of CHF3 molecules in the discharge zone together with decreasing power discharge when initial CHF3 concentration increased as shown in fig 4 (a). Because of total flow rate constant, if CHF3 molecules increased then Nitrogen and oxygen molecules decreased. Moreover, bond-dissociation energy of O-O was 498.36 kJ/mol-1 at 298K. It is low than bond-dis sociation energy of F-CHF2 (539.9 kJ/mol-1) but higher than that of H-CF3 (445.2 kJ/mol-1) at 298 K [21]. At initial CHF3 concentration of 15%, the ratio of CHF3/O2 in the feed was 1/1.19. Several reason above due to conversion of CHF3 depended slightly in the range of initial CHF3. Initial concentration of CHF3 was effective on the concentration of CO2 in the products. However, it did not significantly on the concentration of CO and CHF3 in the products as shown in fig 4 (b). In the detail, concentration of CO2 increased from 4.79% to 14.20% when initial CHF3 concentration increased from 5% to 15%. On the other hand, concentration of CO were increased from 0.18% to 0.38%, while, increasing CHF3 concentration remain from 0.05% to 0.69%, respectively. In fig 4 (c) presented that the selectivity of CO and CO2 were decreased slightly by increasing initial CHF3 concentration in the feed gases. They caused of decreasing carbon balance during increasing initial CHF3 concentration in the feed. As the results, reactant conversion and products selectivity were depending slightly on the initial CHF3 concentration from 5% to 15% in these experiments. Effect of frequency Frequency of applied power is important factor along with voltage. Because they effected on the discharge power (equation 1) and applied power waveform. The effect of frequency on the reaction were investigated under condition of 7 kV applied voltage and 100 ml/min total flow rate with 5% CHF3 concentration in the feed. The results was shown in fig 5. It showed that the conversion of CHF3 increased significantly from 10 to 20 kHz; then it increased slightly at frequency of 30 kHz. While, discharge power increased gradually when frequency increased from 10 to 30 kHz as shown in fig 5(a). One of reason increased CHF3 conversion was increased discharge power when applied frequency increased from 10 to 30 kHz. Applied frequency also effect on the component of products. It was shown in fig 5 (b). Concentration of CO2 increased significantly from 2.89% to 4.79%, while, concentration of CO decreased from 0.36% to 0.18% when applied frequency increased from 10 to 30 kHz. Although, decreased CO concentration rate is twice when applied frequency from 10 to 30 kHz but it was small compared with concentration of CO2 in the products. As the same trend of concentration in products, the selectivity of CO2 increased, while, the selectivity of CO decreased when increased applied frequency as shown in fig 5 (c). The results presented that trend of CO2 and CO selectivity were opposed. It was caused of carbon balance did not change significantly from 10 to 20 kHz. However, carbon balance were increased when applied frequency increased from 20 to 30 kHz. It could be explained by that the selectivity of CO2 increased was more than reducing of CO selectivity at frequency of 30 kHz. Therefore, total molecules of CO and CO2 were increased when increased applied frequency from 20 to 30 kHz. In addition, carbon balance depending on total molecules of CO and CO2 (Equation 3). Consequently, increasing of applied frequency was not only increasing CHF3 conversion and CO2 selectivity but also reduced the selectivity of CO. Conclusion Destruction of CHF3 with zero air by a coaxial dielectric barrier discharge immersed in the electrically insulating oil bath was investigated. Several factors were effect on the reaction has been studied such as applied voltage, frequency and initial reactant concentration. The conversion of CHF3 was improved by increasing applied voltage and frequency; decreasing initial concentration of CHF3 in the feed gases. One of reason was the factors effect on the discharge power in the plasma reaction. The results demonstrated that the reactor was potential for CHF3 decomposing with initial reactant concentration was from 5% to 15% in the feed gases. More 95% of CHF3 in the feed could be destructed to CO, CO2 and so on, herein, total selectivity of CO and CO2 was more than 85% in the products. Acknowledgements This work was supported by the National Research Foundation of Korea (NRF) grant funded by the Korea Government (MEST) (2010-0007450). References [1] D. HoughtonJT, N. GriggsDJ, D. Van der LindenPJ, J. MaskellK, Third Assessment Report of the Intergovernmental Panel on Climate Change. Cambridge University Press, Cambridge (2001). [2] A. McCulloch, Background_240305. pdf [Accessed 15 April 2010] (2005). [3] W. Han, E.M. Kennedy, S.K. Kundu, J.C. Mackie, A.A. Adesina, B.Z. Dlugogorski, J. Fluorine Chem. 131 (2010) 751. [4] P. Zhang, L. Cao, R. Pan, Z. Jiang, K. Qin, Q. Li, Procedia Engineering 62 (2013) 337. [5] N. Nagasaki, Y. Morikuni, K. Kawada, S. Arai, Catal. Today 88 (2004) 121. [6] G. Luo, Y. Luo, J. Qu, New J. Chem. 37 (2013) 3274. [7] H. Sekiguchi, T. Honda, A. Kanzawa, Plasma Chem. Plasma Process. 13 (1993) 463. [8] A.B. Murphy, T. McAllister, Phys. Plasmas 8 (2001) 2565. [9] M.B. Chang, H.M. Lee, Catal. Today 89 (2004) 109. [10] D.H. Kim, Y.S. Mok, S.B. Lee, S.M. Shi, J. Adv. Oxid. Technol. 13 (2010) 36. [11] W. Han, Y. Li, H. Tang, H. Liu, J. Fluorine Chem. 140 (2012) 7. [12] Validation Projects Methodologies: AM0001, Unfccc (2014) Accesed on 01/16 https://cdm.unfccc.int/Projects/Validation/index.html [13] H. Onoda, T. Ohta, J. Tamaki, K. Kojima, Applied Catalysis A: General 288 (2005) 98. [14] W.B. Feaver, J.A. Rossin, Catal. Today 54 (1999) 13. [15] J.Y. Jeon, X.-F. Xu, M.H. Choi, H.Y. Kim, Y.-K. Park, Chem. Commun. (2003) 1244. [16] C.L. Hartz, J.W. Bevan, M.W. Jackson, B.A. Wofford, Environ. Sci. Technol. 32 (1998) 682. [17] B.A. Wofford, M.W. Jackson, C. Hartz, J.W. Bevan, Environ. Sci. Technol. 33 (1999) 1892. [18] D.H. Kim, Y.S. Mok, S.B. Lee, Thin Solid Films 519 (2011) 6960. [19] M.S. Gandhi, Y.S. Mok, J. Environ. Sci. 24 (2012) 1234. [20] L.M. Zhou, B. Xue, U. Kogelschatz, B. Eliasson, Energy Fuels 12 (1998) 1191. [21] D.R. Lide, CRC Handbook of Chemistry and Physics, 90th Edition Internet Version, 1405-1438, CRC Press/Taylor and Francis: Boca Raton, FL, (2010). List of figure Fig.1.Schematic diagram of the experimental setup Fig. 2. Typical signal of the voltage, current, and discharge power (total flow rate = 100 ml/min; CHF3 in feed= 5% of volume; applied voltage= 7 kV; frequency=30 kHz). Fig. 3. Effect of applied voltage on (a) conversion of CHF3 and discharge power, (b) component of products; and (c) carbon balance and selectivity of products (total flow rate = 100 ml/min; CHF3 in feed= 5% of volume; frequency=30 kHz). Fig. 4. Effect of initial concentration of CHF3 on (a) conversion of CHF3 and discharge power; (b) component of products; and (c) carbon balance and selectivity of products (total flow rate = 100 ml/min; applied voltage = 7 kV; frequency=30 kHz). Fig. 5. Effect of frequency on (a) conversion of CHF3 and discharge power; (b) component of products; and (c) carbon balance and selectivity of products (total flow rate = 100 ml/min; CHF3 in feed= 5% of volume; applied voltage = 7 kV). Fig. 1 Fig. 2 Fig. 3 Fig. 4 Fig. 5 1

How to Preserve Endanger Animals

How endangerment of animals can be prevented or overcome. There are many ways to help the endangered animal. One of the most important ways to help threatened animals is to conserve their habitat permanently. These habitats are area such as national parks, national reserves and wilderness areas. There they can live without interference by human activities. Human’s activities such as deforestation, farming, over grazing and development result the soil compaction, erosion, desertification, and alteration of local climatic conditions.These changes make the wildlife ill-adapt to the drastically changed environment. In areas where rare species are present, habitat destruction can quickly force a species to extinction. Besides that, we can also play our role in conserving the wildlife habitat. Controlling the rubbish dumping systematically and give heavy fine to irresponsibility citizen that against the rules. By conserving the wildlife habitats, endangered animal can be saved. Many of the Earth's habitats, animals, plants, insects, and even micro-organisms that we know as rare may not be known at all by future generations.We have the capability, and the responsibility. We must act before it is too late. We carry the responsibility to let our future generation to have a look at those animals which is not by merely in the picture in the book. Furthermore we can join a conservation organisation. There are many community groups working on conservation activities. Different organizations have different objectives—some work to protect a small plot of land or to protect whales, others focus on establishing good environmental policies in local government.If you have a specific area of interest, we can often find an organization that is working to protect the species or habitats we are most concerned about. By joining in, we can support well-organized, ongoing efforts to protect species and habitats. Despite of the scale of the project, we are doing it based on our nature to help the endangered animal. As such, we must do it with our instinct to help these animals. Moreover we must support the 3R slogan – recycle, reduce and reuse. By recycling and reusing as much as we can, we reduce our impact on the environment.Additionally, by reducing the energy we consume, we take a little of the burden off our natural resources. As such, we are encouraged to respond positively towards slogan and plan that is hold by the government, such as the car pool system and taking public transport. On the other hand, we can also do our part to save the wildlife, remember to turn off the tap while brushing teeth and use water-saving devices on toilet, taps and showerhead, saving energy by turning off lights when we are not using it. We can also recycle your toys, books and games by donating them to a hospital, nursery school or children's charity.Try to consume organic vegetables and fruits that are healthier and also organic. We must also avoid buying materials that are made by animals, such as clothing, genuine leather and handbags. Many animals are killed to make human’s luxurious item. Producing food and good we use our existent knowledge. On the other hand, animals and especially rare ones could give us a lot of new attainments from history to bionics. Probably, people wouldn’t have invented an airplane, a submarine of a parachute without surveying of animals.Nowadays, studies are more complex, but scientists still have been inspiring by concealed abilities of animals. Learning about animals in their natural habitat helps us to unveil many things about our evolution. This is due to the interactions between human and animals always stay a connection and dependence in our livings. There are a lot of ways how to save land for endangered animals, but the most important thing is the consciousness of people. While we think only about our prosperity, we are unable to think about true beauty. What is so called the †˜true beauty’?It is actually the awareness of the people to figure out the importance of the endangered animal and how they suffer from being chased out from their habitat and thus being decrease in number and as a result extinction of that species of animal. The government should play a significant role here. Campaign should be hold more frequently and at more places so that more people realise the beauty of this nature and how much our hands have destroyed it and how many animals struggling hard to live without our perception. Strict laws should be enforced to curb people from poaching and lodging, deforestation is also strictly prohibited.Despite of the work carried out by the government, we also can do our role to help the animals. We can voice out about what we concern about and our enthusiasm to government or specific department. So that government will take into consideration that many people are increasing the likelihood that someone will do something about it. Besid es that, we can also share with our family or friends to spread and discuss how to protect and do our best on it. We can also let the people know the endangered animal by posting article in the ewspaper and forums on the internet so that the attention of the public will be attracted to the serious problem that endangered species are facing. In conclusion, we should try our best in several ways so that the endangered wildlife animals will be protected. The measures above should be implemented for the sake of the future generation so that they can also enjoy the values hold by these animals. Not only we humans have the living right but the other species have it too. Pictures of conserved national parks in Malaysia Taman Negara Tunku Abdul Rahman National Park

Communication Structure

Definition: A communication structure is the pattern of interaction that exists in every social system. Examples: In families, mothers tend to interact with children more than fathers do, especially when the children are young, but this pattern may shift as the children get older.

Jewish Religion and Tradition Bar and Bat Mitzvahs and...

Bar and bat Mitzvah both translate to the meaning â€Å"son (or) daughter of the commandment.† The most commonly spoken language of the Jewish people and most people in the Middle East starting in 500 B.C.E – 400 C.E is the vernacular language known as Aramaic (Weinstock 2). The words: bar, bat and mitzvah all come from this language. The term â€Å"bar (bat) mitzvah† refers to two different things: first off, when a boy or girl comes of age (12/13), they have become a â€Å"bar (bat) mitzvah,† and then are recognized by the Jewish tradition as having the same rights as a grown man (Blas 1, Weinstock 2). They are now both responsible for the decisions and actions they make. The second thing it refers to is the religious ceremony that accompanies them†¦show more content†¦For more religious Jewish people, it is a pathway into the reasons why they do what they do in situations such as celebrating and observing different holidays. For example, a few weeks ago was a holiday we celebrate called Passover, in the Torah known as Pesach. Some people believe they know more about this holiday than they actually do. The Torah tells us about the deeper meaning of Passover, and the story behind its meaning. If it weren’t for the Torah, we wouldn’t know that the actual meaning behind it is because God â€Å"passed over† the houses of the Jews when he was told to slay the first born of Egypt. We also wouldn’t know why on this holiday we only eat matzah, the unleavened bread, but the Torah tells us the story about how the Jews had to make this bread in the time they had before they had to make their flight from Egypt. The Torah, so to say, is a huge book of stories for us to read whenever we want to learn a new sense of our religion and hear the stories from our people. A lot of people don’t know, but within the bar and bat mitzvah ceremony one can be a part of a huge storytelling ceremony as well. When th e bar and bat mitzvah are called up to the Torah, they are assigned a certain Torah portion or a Haftorah. The Torah portion is from the five books of Moses, and the Haftorah comes from the book of the prophets. The Torah portion and Haftorah one is given depends on the day they were born and the day they will be having their services.